Solid-solid phase interconversion in an organic conductor crystal: hydrogen-bond-mediated dynamic changes in π-stacked molecular arrangement and physical properties

Abstract

Solid–solid phase interconversion was observed in an organic conductor based on a hydrogen-bonded (H-bonded) TTF (tetrathiafulvalene) molecular unit, in which the π-stacked molecular arrangement and physical properties were dynamically changed with unexpected transformation of the H-bond unit between the planar and bent forms.