Issue 15, 2015
From the journal:

Chemical Communications

Pd(0)-catalyzed chemoselective construction of spirocarbocycles via an alkyne insertion/β-naphthol dearomatization cascade†

Huayu Zheng,‡a   Lu Bai,‡a   Jingjing Liu,a   Jiang Nan,a   Zhijun Zuo,a   Liu Yang,a   Yaoyu Wanga  and  Xinjun Luan*a  

* Corresponding authors

a Key Laboratory of Synthetic and Natural Functional Molecular Chemistry of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, China
E-mail: xluan@nwu.edu.cn

Abstract

A microwave-assisted Pd(0)-catalyzed alkyne migratory insertion/β-naphthol dearomatization cascade process has been accomplished to access a variety of spirocyclic compounds bearing all-carbon quaternary stereogenic centers in high yields with excellent chemoselectivities.

Graphical abstract: Pd(0)-catalyzed chemoselective construction of spirocarbocycles via an alkyne insertion/β-naphthol dearomatization cascade

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Article information

DOI
https://doi.org/10.1039/C4CC09099C
Article type
Communication
Submitted
14 Nov 2014
Accepted
09 Jan 2015
First published
09 Jan 2015

Chem. Commun., 2015,51, 3061-3064

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Pd(0)-catalyzed chemoselective construction of spirocarbocycles via an alkyne insertion/β-naphthol dearomatization cascade

H. Zheng, L. Bai, J. Liu, J. Nan, Z. Zuo, L. Yang, Y. Wang and X. Luan, Chem. Commun., 2015, 51, 3061 DOI: 10.1039/C4CC09099C

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