Issue 17, 2015

Mechanically stable, hierarchically porous Cu3(btc)2 (HKUST-1) monoliths via direct conversion of copper(ii) hydroxide-based monoliths

Abstract

The synthesis of highly crystalline macro-meso-microporous monolithic Cu3(btc)2 (HKUST-1; btc3− = benzene-1,3,5-tricarboxylate) is demonstrated by direct conversion of Cu(OH)2-based monoliths while preserving the characteristic macroporous structure. The high mechanical strength of the monoliths is promising for possible applications to continuous flow reactors.

Graphical abstract: Mechanically stable, hierarchically porous Cu3(btc)2 (HKUST-1) monoliths via direct conversion of copper(ii) hydroxide-based monoliths

Supplementary files

Article information

Article type
Communication
Submitted
04 Dec 2014
Accepted
02 Jan 2015
First published
02 Jan 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 3511-3514

Author version available

Mechanically stable, hierarchically porous Cu3(btc)2 (HKUST-1) monoliths via direct conversion of copper(II) hydroxide-based monoliths

N. Moitra, S. Fukumoto, J. Reboul, K. Sumida, Y. Zhu, K. Nakanishi, S. Furukawa, S. Kitagawa and K. Kanamori, Chem. Commun., 2015, 51, 3511 DOI: 10.1039/C4CC09694K

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