Construction of a supported Ru complex on bifunctional MOF-253 for photocatalytic CO2 reduction under visible light

Dengrong Sun; Yanhong Gao; Jinlong Fu; Xianchong Zeng; Zhongning Chen; Zhaohui Li

doi:10.1039/C4CC09797A

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Construction of a supported Ru complex on bifunctional MOF-253 for photocatalytic CO₂ reduction under visible light†

Dengrong Sun,^a Yanhong Gao,^a Jinlong Fu,^a Xianchong Zeng,^b Zhongning Chen^b and Zhaohui Li*^a

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* Corresponding authors

^a Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, P. R. China
E-mail: zhaohuili1969@yahoo.com

^b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou, P. R. China

Abstract

A MOF-253 supported active Ru carbonyl complex (MOF-253–Ru(CO)₂Cl₂) was constructed for photocatalytic CO₂ reduction under visible light irradiation. Its performance can be further improved by immobilization as a photosensitizer. This study highlights the great potential of using MOFs as a solid ligand and platform for the assembly of a complicated catalytic system.

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Article information

DOI: https://doi.org/10.1039/C4CC09797A
Article type: Communication
Submitted: 08 Dec 2014
Accepted: 02 Jan 2015
First published: 02 Jan 2015

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Chem. Commun., 2015,51, 2645-2648

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Construction of a supported Ru complex on bifunctional MOF-253 for photocatalytic CO₂ reduction under visible light

D. Sun, Y. Gao, J. Fu, X. Zeng, Z. Chen and Z. Li, Chem. Commun., 2015, 51, 2645 DOI: 10.1039/C4CC09797A

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