Issue 16, 2015

Silver-mediated direct phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides

Abstract

A silver nitrate-mediated, efficient phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides was developed. This process provides a convenient route for the synthesis of a variety of 2-diarylphosphoryl benzothiazoles and thiazoles which are promising precursors of a series of hemilabile P,N-ligands with small bite angles.

Graphical abstract: Silver-mediated direct phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides

Associated articles

Supplementary files

Article information

Article type
Communication
Submitted
16 Dec 2014
Accepted
20 Jan 2015
First published
28 Jan 2015

Chem. Commun., 2015,51, 3450-3453

Silver-mediated direct phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides

H. Zhang, W. Lin, Z. Wu, W. Ruan and T. Wen, Chem. Commun., 2015, 51, 3450 DOI: 10.1039/C4CC10017D

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