Issue 14, 2015

Regioselective electrophilic borylation of haloarenes

Abstract

Haloarenes undergo direct borylation using amine : BCl3 : AlCl3 in the ratio of 1 : 1 : 2. After esterification the pinacol boronate esters are isolated in good yield with regioselectivity controlled by steric and electronic effects.

Graphical abstract: Regioselective electrophilic borylation of haloarenes

Supplementary files

Article information

Article type
Communication
Submitted
19 Dec 2014
Accepted
02 Jan 2015
First published
05 Jan 2015

Chem. Commun., 2015,51, 2878-2881

Author version available

Regioselective electrophilic borylation of haloarenes

A. Del Grosso, J. Ayuso Carrillo and M. J. Ingleson, Chem. Commun., 2015, 51, 2878 DOI: 10.1039/C4CC10153G

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