Issue 19, 2015

A nonheme manganese(iv)–oxo species generated in photocatalytic reaction using water as an oxygen source

Abstract

A nonheme manganese(IV)–oxo complex, [MnIV(O)(BQCN)]2+, was generated in the photochemical and chemical oxidation of [MnII(BQCN)]2+ with water as an oxygen source, respectively. The photocatalytic oxidation of organic substrates, such as alcohol and sulfide, by [MnII(BQCN)]2+ has been demonstrated in both neutral and acidic media.

Graphical abstract: A nonheme manganese(iv)–oxo species generated in photocatalytic reaction using water as an oxygen source

Supplementary files

Article information

Article type
Communication
Submitted
30 Dec 2014
Accepted
29 Jan 2015
First published
29 Jan 2015

Chem. Commun., 2015,51, 4013-4016

Author version available

A nonheme manganese(IV)–oxo species generated in photocatalytic reaction using water as an oxygen source

X. Wu, X. Yang, Y. Lee, W. Nam and L. Sun, Chem. Commun., 2015, 51, 4013 DOI: 10.1039/C4CC10411K

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