Issue 37, 2014
From the journal:

CrystEngComm

Two porous metal–organic frameworks containing zinc–calcium clusters and calcium cluster chains†

Kyungkyou Noh,a   Nakeun Ko,a   Hye Jeong Park,*a   SangYoun Park*b  and  Jaheon Kim*a  

* Corresponding authors

a Institute for Integrative Basic Sciences, Department of Chemistry, Soongsil University, Seoul 156-743, Korea
E-mail: parkhyejeong83@gmail.com, jaheon@ssu.ac.kr
Fax: +82 2 824 4383
Tel: +82 2 820 0459

b School of Systems Biomedical Science, Soongsil University, Seoul 156-743, Korea
E-mail: psy@ssu.ac.kr
Fax: +82 2 824 4383
Tel: +82 2 820 0459

Abstract

A two-dimensional metal–organic framework (MOF) containing both Zn(II) and Ca(II) centres and a three-dimensional MOF containing only Ca(II) centres have the largest surface areas (BET 1560 and 914 m2 g−1, respectively) among the reported Ca-based MOFs and also exhibit high gas uptake up to 1 bar for H2 at 77 K and CO2 at 298 K.

Graphical abstract: Two porous metal–organic frameworks containing zinc–calcium clusters and calcium cluster chains

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Article information

DOI
https://doi.org/10.1039/C4CE01237B
Article type
Communication
Submitted
17 Jun 2014
Accepted
28 Jul 2014
First published
29 Jul 2014

CrystEngComm, 2014,16, 8664-8668

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Two porous metal–organic frameworks containing zinc–calcium clusters and calcium cluster chains

K. Noh, N. Ko, H. J. Park, S. Park and J. Kim, CrystEngComm, 2014, 16, 8664 DOI: 10.1039/C4CE01237B

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