Issue 38, 2014

A uniform approach to the description of multicenter bonding

Abstract

A novel method for investigating the multicenter bonding patterns in molecular systems by means of the so-called Electron Density of Delocalized Bonds (EDDB) is introduced and discussed. The EDDB method combines the concept of Jug's bond-order orbitals and the indirect (“through-bridge”) interaction formalism and opens up new opportunities for studying the interplay between different atomic interactions as well as their impact on both local and global resonance stabilization in systems of conjugated bonds. Using several illustrative examples we demonstrate that the EDDB approach allows for a reliable quantitative description of diverse multicenter delocalization phenomena (with special regard to evaluation of the aromatic stabilization in molecular systems) within the framework of a consistent theoretical paradigm.

Graphical abstract: A uniform approach to the description of multicenter bonding

Article information

Article type
Paper
Submitted
04 Jul 2014
Accepted
10 Aug 2014
First published
11 Aug 2014

Phys. Chem. Chem. Phys., 2014,16, 20514-20523

A uniform approach to the description of multicenter bonding

D. W. Szczepanik, M. Andrzejak, K. Dyduch, E. Żak, M. Makowski, G. Mazur and J. Mrozek, Phys. Chem. Chem. Phys., 2014, 16, 20514 DOI: 10.1039/C4CP02932A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements