Issue 16, 2014

High valence 3p and transition metal based MOFs

Abstract

This article focuses on high valence 3p and transition metal based metal organic frameworks. In the first part we will discuss the complex solution chemistry of these metals which makes this sub-class of MOFs more of a challenge than the traditional low valence metal based MOFs. This is followed by a short review of the different classes of solids based on phosphonates, carboxylates and other linkers. Finally, we report some of the most relevant properties of these solids such as their chemical or thermal stability as well as their catalytic, redox- and photo-activities.

Graphical abstract: High valence 3p and transition metal based MOFs

Article information

Article type
Review Article
Submitted
20 Feb 2014
First published
20 Jun 2014

Chem. Soc. Rev., 2014,43, 6097-6115

Author version available

High valence 3p and transition metal based MOFs

T. Devic and C. Serre, Chem. Soc. Rev., 2014, 43, 6097 DOI: 10.1039/C4CS00081A

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