Issue 1, 2015
From the journal:

Catalysis Science & Technology

Selective sulfoxidation with hydrogen peroxide catalysed by a titanium catalyst†

Lorena Postigo,a   Maria Ventura,b   Tomás Cuenca,b   Gerardo Jiménez*b  and  Beatriz Royo*a  

* Corresponding authors

a Instituto de Tecnología Química e Biológica da Universidade Nova de Lisboa. Av. da República, EAN, 2780-157 Oeiras, Portugal
E-mail: broyo@itqb.unl.pt

b Departamento de Química Orgánica y Química Inorgánica, Universidad de Alcalá, Campus Universitario, 28871 Alcalá de Henares, Spain

Abstract

A moisture-tolerant cyclopentadienyl–silsesquioxane titanium complex efficiently catalyses the selective oxidation of various types of sulfides to either sulfoxides (TOFs up to 32 530 h−1) or sulfones with H2O2 (30% in water) under mild conditions.

Graphical abstract: Selective sulfoxidation with hydrogen peroxide catalysed by a titanium catalyst

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Article information

DOI
https://doi.org/10.1039/C4CY00965G
Article type
Paper
Submitted
25 Jul 2014
Accepted
20 Aug 2014
First published
21 Aug 2014

Catal. Sci. Technol., 2015,5, 320-324

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Selective sulfoxidation with hydrogen peroxide catalysed by a titanium catalyst

L. Postigo, M. Ventura, T. Cuenca, G. Jiménez and B. Royo, Catal. Sci. Technol., 2015, 5, 320 DOI: 10.1039/C4CY00965G

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