Issue 22, 2014
From the journal:

Dalton Transactions

A cationic copper(i) iodide cluster MOF exhibiting unusual ligand assisted thermochromism†

Ashok Yadav,a   Anant Kumar Srivastava,a   Ayyakkalai Balamurugana  and  Ramamoorthy Boomishankar*a  

* Corresponding authors

a Mendeleev Block, Chemistry Division, Indian Institute of Science Education and Research (IISER), Pune, Dr. Homi Bhabha Road, Pune, India
E-mail: boomi@iiserpune.ac.in

Abstract

By employing a tridentate thiophosphoramide ligand, [(NHAQ)3P[double bond, length as m-dash]S] (AQ = 3-quinolinyl), a cationic MOF, 1 {[Cu6I5(L1)2](OH)·3DMF·2.5MeOH}n, was synthesized. Photo-physical studies on the 2D-MOF 1 showed an unusual thermochromic behaviour emitting a blue fluorescence at 298 K due to the AQ chromophore and an orange-yellow phosphorescence at 77 K due to the [Cu6I5]+ unit.

Graphical abstract: A cationic copper(i) iodide cluster MOF exhibiting unusual ligand assisted thermochromism

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4DT00050A
Article type
Communication
Submitted
07 Jan 2014
Accepted
21 Mar 2014
First published
28 Mar 2014

Dalton Trans., 2014,43, 8166-8169

Author version available

Download author version (PDF)

Permissions

Request permissions

A cationic copper(I) iodide cluster MOF exhibiting unusual ligand assisted thermochromism

A. Yadav, A. K. Srivastava, A. Balamurugan and R. Boomishankar, Dalton Trans., 2014, 43, 8166 DOI: 10.1039/C4DT00050A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements