A highly selective colorimetric chemosensor for cobalt(ii) ions based on a tripodal amide ligand

Abstract

A tripodal amide based ligand, tris-{(2-carbamoyl-5-carbomethoxy-pyridine)-2-ethyl}amine (H₃L, 1), was synthesized and structurally characterized by single crystal X-ray diffraction. Investigation of the cation recognition behavior showed that the ligand has selective colorimetric sensing properties for cobalt(II) ions by an obvious color change from colorless to yellow. To investigate the sensing mechanism of H₃L for Co²⁺ ions, UV-vis absorption spectroscopy and single-crystal structural analysis were performed. The mixture of the ligand and cobalt(II) ions displayed selective colorimetric sensing properties for weak acid anions, such as CO₃²⁻, Ac⁻, HCO₃⁻, SO₃²⁻, and PO₄³⁻. Detailed ¹H NMR experiments revealed that the basicity of the anions played an important role in the intensity of the interaction between the ligand and anions. The structures of compounds CoL (2), Co-Ac-HL (3), H₄L-NO₃ (4), and H₄L-ClO₄ (5) were also determined by single crystal diffraction studies.