Issue 28, 2014

Gold(iii) compounds containing a chelating, dicarbanionic ligand derived from 4,4′-di-tert-butylbiphenyl

Abstract

An oligomeric gold(III) compound containing dicarbanionic chelating 4,4′-di-tert-butylbiphenyl was prepared via transmetallation using the corresponding organotin(IV) compound. The reactivity of the chloro-bridged oligomer with various species including neutral N-, P-, and C-donor ligands as well as monoanionic S- and Se-ligands was investigated. Some of the products were characterised by X-ray crystallography. The photophysical properties of two derivatives were studied.

Graphical abstract: Gold(iii) compounds containing a chelating, dicarbanionic ligand derived from 4,4′-di-tert-butylbiphenyl

Supplementary files

Article information

Article type
Paper
Submitted
14 Mar 2014
Accepted
23 May 2014
First published
27 May 2014
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2014,43, 11059-11066

Author version available

Gold(III) compounds containing a chelating, dicarbanionic ligand derived from 4,4′-di-tert-butylbiphenyl

B. David, U. Monkowius, J. Rust, C. W. Lehmann, L. Hyzak and F. Mohr, Dalton Trans., 2014, 43, 11059 DOI: 10.1039/C4DT00778F

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