Issue 46, 2014
From the journal:

Dalton Transactions

Anion-controlled self-assembly of two NLO-active dinuclear and molecular square Cu(ii) enantiomeric pairs: from antiferromagnetic to ferromagnetic coupling†

Xi-Li Li,*a   Jia-Long Kang,a   Xue-Li Zhang,a   Hong-Ping Xiao,*c   Ai-Ling Wang,a   Liming Zhou,a   Shao-Ming Fanga  and  Cai-Ming Liu*b  

* Corresponding authors

a Henan Provincial Key Laboratory of Surface and Interface Science, Collaborative Innovation Center of Environmental Pollution Control and Ecological Restoration, Zhengzhou University of Light Industry, Zhengzhou 450002, China
E-mail: lixl@zzuli.edu.cn

b Beijing National Laboratory for Molecular Science, Institution of Chemistry, Chinese Academy of Science, Center for Molecular Science, Beijing 100190, China
E-mail: cmliu@iccas.ac.cn

c College of Chemistry and Material Engineering, Wenzhou University, Wenzhou 325035, China
E-mail: hp_xiao@126.com

Abstract

Two second-order nonlinear optically (NLO)-active dinuclear and square Cu(II) enantiomeric pairs were obtained via the self-assemblies of enantiopure linear bis-bidentate ligands with different copper(II) salts under the identical reaction conditions. Their magnetic properties are switched from antiferromagnetic to ferromagnetic coupling.

Graphical abstract: Anion-controlled self-assembly of two NLO-active dinuclear and molecular square Cu(ii) enantiomeric pairs: from antiferromagnetic to ferromagnetic coupling

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Article information

DOI
https://doi.org/10.1039/C4DT01671H
Article type
Communication
Submitted
06 Jun 2014
Accepted
04 Aug 2014
First published
04 Aug 2014

Dalton Trans., 2014,43, 17226-17229

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Anion-controlled self-assembly of two NLO-active dinuclear and molecular square Cu(II) enantiomeric pairs: from antiferromagnetic to ferromagnetic coupling

X. Li, J. Kang, X. Zhang, H. Xiao, A. Wang, L. Zhou, S. Fang and C. Liu, Dalton Trans., 2014, 43, 17226 DOI: 10.1039/C4DT01671H

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