Issue 38, 2014

Half-sandwich scandium boryl complexes bearing a silylene-linked cyclopentadienyl-amido ligand

Abstract

A boryl scandium complex supported by the silylene-linked cyclopentadienyl-amido ligand was synthesized for the first time, which on reaction with nitric oxide (NO) afforded a novel scandium boryldiazeniumdiolate [ON(boryl)NO] complex.

Graphical abstract: Half-sandwich scandium boryl complexes bearing a silylene-linked cyclopentadienyl-amido ligand

Supplementary files

Article information

Article type
Communication
Submitted
10 Jun 2014
Accepted
14 Jul 2014
First published
16 Jul 2014

Dalton Trans., 2014,43, 14215-14218

Author version available

Half-sandwich scandium boryl complexes bearing a silylene-linked cyclopentadienyl-amido ligand

B. Wang, M. Nishiura, J. Cheng and Z. Hou, Dalton Trans., 2014, 43, 14215 DOI: 10.1039/C4DT01725K

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