Issue 44, 2014
From the journal:

Dalton Transactions

Synthesis, structures, and reactivity of the base-stabilized silanone molybdenum complexes†

Takako Muraoka,a   Keisuke Abe,a   Haruhiko Kimura,a   Youhei Haga,a   Keiji Ueno*a  and  Yusuke Sunadab  

* Corresponding authors

a Division of Molecular Science, Graduate School of Science and Technology, Gunma University, Kiryu 376-8515, Japan
E-mail: ueno@gunma-u.ac.jp

b Institute for Materials Chemistry and Engineering, and Graduate School of Engineering Sciences, Kyushu University, Kasuga, Fukuoka 816-8580, Japan

Abstract

Base-stabilized silanone molybdenum complexes were synthesized by the oxygenation of the M[double bond, length as m-dash]Si bond in the silyl(silylene)molybdenum complex with 1 eq. of PNO in the presence of Lewis base L. The PNO-coordinated silanone complex (L = PNO) was converted to cis-[Cp*(OC)2Mo{OSiMes2(OSiMe3)}(PMe3)] in the presence of excess PMe3.

Graphical abstract: Synthesis, structures, and reactivity of the base-stabilized silanone molybdenum complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4DT02159B
Article type
Communication
Submitted
16 Jul 2014
Accepted
22 Sep 2014
First published
23 Sep 2014

Dalton Trans., 2014,43, 16610-16613

Author version available

Download author version (PDF)

Permissions

Request permissions

Synthesis, structures, and reactivity of the base-stabilized silanone molybdenum complexes

T. Muraoka, K. Abe, H. Kimura, Y. Haga, K. Ueno and Y. Sunada, Dalton Trans., 2014, 43, 16610 DOI: 10.1039/C4DT02159B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements