Issue 43, 2014
From the journal:

Dalton Transactions

Water-exchange rates of lanthanide ions in an ionic liquid†

Zhijin Lin,a   Megan L. Shelby,b   Dugan Hayes,c   Kelly A. Fransted,c   Lin X. Chenbc  and  Matthew J. Allen*a  

* Corresponding authors

a Department of Chemistry, Wayne State University, 5101 Cass Avenue, Detroit, MI 48202, USA
E-mail: mallen@chem.wayne.edu

b Chemistry Department, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA

c Chemical Science and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439, USA

Abstract

The first ligand-exchange rate measurements of lanthanide ions in an ionic liquid are reported here. The trend of water-exchange rates in the ionic liquid is the opposite of the trend in water.

Graphical abstract: Water-exchange rates of lanthanide ions in an ionic liquid

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Article information

DOI
https://doi.org/10.1039/C4DT02492C
Article type
Communication
Submitted
15 Aug 2014
Accepted
19 Sep 2014
First published
01 Oct 2014

Dalton Trans., 2014,43, 16156-16159

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Water-exchange rates of lanthanide ions in an ionic liquid

Z. Lin, M. L. Shelby, D. Hayes, K. A. Fransted, L. X. Chen and M. J. Allen, Dalton Trans., 2014, 43, 16156 DOI: 10.1039/C4DT02492C

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