Issue 46, 2014

Arene-ligated heteroleptic terphenolate complexes of thorium

Abstract

Bulky terphenolate ligands allow the synthesis of rare heteroleptic thorium chloride, and borohydride complexes; in the absence of donor solvents, the terphenolate ligands protect the metal ions through neutral Th–η6-arene interactions in a thorium bis(arene) sandwich motif.

Graphical abstract: Arene-ligated heteroleptic terphenolate complexes of thorium

Supplementary files

Article information

Article type
Paper
Submitted
28 Sep 2014
Accepted
15 Oct 2014
First published
22 Oct 2014

Dalton Trans., 2014,43, 17416-17421

Author version available

Arene-ligated heteroleptic terphenolate complexes of thorium

J. McKinven, G. S. Nichol and P. L. Arnold, Dalton Trans., 2014, 43, 17416 DOI: 10.1039/C4DT02995J

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