Issue 7, 2015

Structural and magnetic properties of oxyquinolinate clusters of cobalt(ii) and manganese(ii) and serendipitous intake of carbonate during synthesis

Abstract

During transformation of a tetra-nuclear cobalt oxiquinolinate cluster to a deca-nuclear cobalt oxyquinolinate cluster, serendipitous intake of a carbonate ion was observed. By following a similar synthetic path, a deca-nuclear manganese oxyquinolinate cluster was prepared. These clusters show anti-ferromagnetic behavior.

Graphical abstract: Structural and magnetic properties of oxyquinolinate clusters of cobalt(ii) and manganese(ii) and serendipitous intake of carbonate during synthesis

Supplementary files

Article information

Article type
Communication
Submitted
29 Sep 2014
Accepted
07 Jan 2015
First published
07 Jan 2015

Dalton Trans., 2015,44, 2964-2969

Author version available

Structural and magnetic properties of oxyquinolinate clusters of cobalt(II) and manganese(II) and serendipitous intake of carbonate during synthesis

P. Khakhlary, C. E. Anson, A. Mondal, A. K. Powell and J. B. Baruah, Dalton Trans., 2015, 44, 2964 DOI: 10.1039/C4DT02999B

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