Issue 1, 2015
From the journal:

Dalton Transactions

1,1-Carboboration to tellurium–boron intramolecular frustrated Lewis pairs†

Fu An Tsaoa  and  Douglas W. Stephan*a  

* Corresponding authors

a Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario, Canada
E-mail: dstephan@chem.utoronto.ca

Abstract

The tellurium acetylide Ph(CH2)2TeCCPh reacts with boranes via 1,1-carboboration to give a series of borylated vinyl telluroethers. The product Ph(CH2)2TeC(Ph)C(C6F5) B(C6F5)2 reacts with phenylacetylene and iodine to give novel tellurium–boron heterocyclic compounds.

Graphical abstract: 1,1-Carboboration to tellurium–boron intramolecular frustrated Lewis pairs

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Article information

DOI
https://doi.org/10.1039/C4DT03241A
Article type
Communication
Submitted
20 Oct 2014
Accepted
01 Nov 2014
First published
12 Nov 2014

Dalton Trans., 2015,44, 71-74

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1,1-Carboboration to tellurium–boron intramolecular frustrated Lewis pairs

F. A. Tsao and D. W. Stephan, Dalton Trans., 2015, 44, 71 DOI: 10.1039/C4DT03241A

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