Issue 3, 2015

Facile synthesis of [(NHC)MX(cod)] and [(NHC)MCl(CO)2] (M = Rh, Ir; X = Cl, I) complexes

Abstract

The reactions of [MCl(cod)]2 (M = Rh, Ir) with different NHC·HX (X = Cl, I), K2CO3 in technical grade acetone under air provide simple access to various [(NHC)MX(cod)] complexes; a facile one-pot synthesis of [(NHC)MCl(CO)2] (M = Rh, Ir) is also reported.

Graphical abstract: Facile synthesis of [(NHC)MX(cod)] and [(NHC)MCl(CO)2] (M = Rh, Ir; X = Cl, I) complexes

Supplementary files

Article information

Article type
Communication
Submitted
10 Nov 2014
Accepted
12 Nov 2014
First published
12 Nov 2014
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2015,44, 891-893

Author version available

Facile synthesis of [(NHC)MX(cod)] and [(NHC)MCl(CO)2] (M = Rh, Ir; X = Cl, I) complexes

R. Savka and H. Plenio, Dalton Trans., 2015, 44, 891 DOI: 10.1039/C4DT03449J

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