Issue 8, 2014
From the journal:

Green Chemistry

Transition-metal-free synthesis of vinyl sulfones via tandem cross-decarboxylative/coupling reactions of sodium sulfinates and cinnamic acids†

Yanli Xu,a   Xiaodong Tang,a   Weigao Hu,a   Wanqing Wua  and  Huanfeng Jiang*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China
E-mail: jianghf@scut.edu.cn
Fax: +86 20-87112906
Tel: +86 20-87112906

Abstract

A transition-metal-free synthesis of vinyl sulfones, utilizing sodium sulfinates and cinnamic acids through tandem cross-decarboxylative/coupling reactions, has been developed. This transformation is simple, efficient and environmentally benign, with a wide range of substrate scope and exceptional functional group tolerance.

Graphical abstract: Transition-metal-free synthesis of vinyl sulfones via tandem cross-decarboxylative/coupling reactions of sodium sulfinates and cinnamic acids

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Article information

DOI
https://doi.org/10.1039/C4GC00542B
Article type
Communication
Submitted
27 Mar 2014
Accepted
23 Apr 2014
First published
25 Apr 2014

Green Chem., 2014,16, 3720-3723

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Transition-metal-free synthesis of vinyl sulfones via tandem cross-decarboxylative/coupling reactions of sodium sulfinates and cinnamic acids

Y. Xu, X. Tang, W. Hu, W. Wu and H. Jiang, Green Chem., 2014, 16, 3720 DOI: 10.1039/C4GC00542B

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