Issue 24, 2014
From the journal:

Organic & Biomolecular Chemistry

Gold-catalyzed tandem Diels–Alder reactions of enynals/enynones with alkenes: generation and trapping of cyclic o-QDMs†

Shifa Zhu,*a   Lang Hua  and  Huanfeng Jianga  

* Corresponding authors

a School of Chemistry and Chemical Engineering, South China, University of Technology, Guangzhou City, Guangdong Province, China
E-mail: zhusf@scut.edu.cn
Fax: +86-20-87112906

Abstract

An efficient gold-catalyzed method to generate the highly reactive cyclic o-QDM species from the enynal/enynone and alkene is reported. This method allows rapid access to a variety of structurally unique propeller-like products through tandem Diels–Alder reactions.

Graphical abstract: Gold-catalyzed tandem Diels–Alder reactions of enynals/enynones with alkenes: generation and trapping of cyclic o-QDMs

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Article information

DOI
https://doi.org/10.1039/C4OB00321G
Article type
Paper
Submitted
12 Feb 2014
Accepted
18 Feb 2014
First published
18 Feb 2014

Org. Biomol. Chem., 2014,12, 4104-4111

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Gold-catalyzed tandem Diels–Alder reactions of enynals/enynones with alkenes: generation and trapping of cyclic o-QDMs

S. Zhu, L. Hu and H. Jiang, Org. Biomol. Chem., 2014, 12, 4104 DOI: 10.1039/C4OB00321G

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