Issue 26, 2014
From the journal:

Organic & Biomolecular Chemistry

TEMPO-mediated allylic C–H amination with hydrazones†

Xu Zhua  and  Shunsuke Chiba*a  

* Corresponding authors

a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore
E-mail: shunsuke@ntu.edu.sg
Fax: +65-67911961

Abstract

TEMPO-mediated reactions of alkenyl hydrazones afforded azaheterocycles via sp3 C–H allylic amination. The transformation is featured by a sequence of remote allylic H-radical shift and allylic homolytic substitution with hydrazone radicals.

Graphical abstract: TEMPO-mediated allylic C–H amination with hydrazones

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Article information

DOI
https://doi.org/10.1039/C4OB00839A
Article type
Communication
Submitted
23 Apr 2014
Accepted
10 May 2014
First published
13 May 2014

Org. Biomol. Chem., 2014,12, 4567-4570

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TEMPO-mediated allylic C–H amination with hydrazones

X. Zhu and S. Chiba, Org. Biomol. Chem., 2014, 12, 4567 DOI: 10.1039/C4OB00839A

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