Issue 4, 2015

Metal-catalyzed formation of 1,3-cyclohexadienes: a catalyst-dependent reaction

Abstract

A metal-dependent and complementary catalytic method to synthesize the cyclohexadienes has been developed. When gold or indium salts were used as catalysts, 1,3-cyclohexadiene (1,3-CHD) could be obtained; when Cu(OTf)2 was used as the catalyst, however, another isomer 2,4-cyclohexadiene (2,4-CHD) was furnished instead.

Graphical abstract: Metal-catalyzed formation of 1,3-cyclohexadienes: a catalyst-dependent reaction

Supplementary files

Article information

Article type
Paper
Submitted
10 Sep 2014
Accepted
15 Nov 2014
First published
18 Nov 2014

Org. Biomol. Chem., 2015,13, 1225-1233

Author version available

Metal-catalyzed formation of 1,3-cyclohexadienes: a catalyst-dependent reaction

S. Zhu, X. Huang, T. Zhao, T. Ma and H. Jiang, Org. Biomol. Chem., 2015, 13, 1225 DOI: 10.1039/C4OB01922A

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