Issue 47, 2014
From the journal:

Organic & Biomolecular Chemistry

Silver-mediated oxidative vinylic C–H bond sulfenylation of enamides with disulfides†

Luo Yang,*a   Qing Wen,a   Fuhong Xiaoa  and  Guo-Jun Deng*a  

* Corresponding authors

a Key Laboratory for Environmentally Friendly Chemistry and Application of the Ministry of Education, College of Chemistry, Xiangtan University, Hunan, China
E-mail: yangluo@xtu.edu.cn, gjdeng@xtu.edu.cn
Tel: +86-731-5829-8351

Abstract

A silver-mediated oxidative vinylic C–H bond sulfenylation of enamides was developed. This method is compatible with diaryl and dialkyl disulfides to deliver biologically precious chalcogenated olefins efficiently. A plausible non-chain radical mechanism was proposed for understanding this novel sulfenylation based on the mechanistic studies.

Graphical abstract: Silver-mediated oxidative vinylic C–H bond sulfenylation of enamides with disulfides

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Article information

DOI
https://doi.org/10.1039/C4OB01970A
Article type
Communication
Submitted
16 Sep 2014
Accepted
15 Oct 2014
First published
15 Oct 2014

Org. Biomol. Chem., 2014,12, 9519-9523

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Silver-mediated oxidative vinylic C–H bond sulfenylation of enamides with disulfides

L. Yang, Q. Wen, F. Xiao and G. Deng, Org. Biomol. Chem., 2014, 12, 9519 DOI: 10.1039/C4OB01970A

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