Issue 22, 2014
From the journal:

Polymer Chemistry

Living polymerization of arylisocyanide initiated by the phenylethynyl palladium(ii) complex†

Ya-Xin Xue,a   Jia-Li Chen,a   Zhi-Qiang Jiang,a   Zhipeng Yu,a   Na Liu,a   Jun Yin,a   Yuan-Yuan Zhua  and  Zong-Quan Wu*a  

* Corresponding authors

a Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology and Anhui Key Laboratory of Advanced Functional Materials and Devices, Hefei 230009, China
E-mail: zqwu@hfut.edu.cn

Abstract

A family of air-stable phenylethynyl palladium complexes was unexpectedly found to initiate the polymerization of phenyl isocyanide in a living/controlled chain growth manner, affording well-defined, stereoregular poly(phenyl isocyanide)s in high yield with controlled molecular weights and narrow molecular weight distributions.

Graphical abstract: Living polymerization of arylisocyanide initiated by the phenylethynyl palladium(ii) complex

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Article information

DOI
https://doi.org/10.1039/C4PY01023J
Article type
Communication
Submitted
25 Jul 2014
Accepted
08 Aug 2014
First published
11 Aug 2014

Polym. Chem., 2014,5, 6435-6438

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Living polymerization of arylisocyanide initiated by the phenylethynyl palladium(II) complex

Y. Xue, J. Chen, Z. Jiang, Z. Yu, N. Liu, J. Yin, Y. Zhu and Z. Wu, Polym. Chem., 2014, 5, 6435 DOI: 10.1039/C4PY01023J

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