Issue 9, 2014
From the journal:

Organic Chemistry Frontiers

Palladium(ii)-catalyzed direct conversion of allyl arenes into alkenyl nitriles†

Zhibin Shu,a   Yujing Zhou,a   Yan Zhanga  and  Jianbo Wang*ab  

* Corresponding authors

a Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China
E-mail: wangjb@pku.edu.cn
Fax: (+86) 10-6275-7248
Tel: (+86) 10-6275-1708

b State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Abstract

A mild palladium-catalyzed ammoxidation approach, which leads to the formation of the C[triple bond, length as m-dash]N triple bond in an allyl group, has been developed to directly convert allylarenes into alkenyl nitriles.

Graphical abstract: Palladium(ii)-catalyzed direct conversion of allyl arenes into alkenyl nitriles

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Article information

DOI
https://doi.org/10.1039/C4QO00218K
Article type
Research Article
Submitted
31 Jul 2014
Accepted
05 Sep 2014
First published
10 Sep 2014

Org. Chem. Front., 2014,1, 1123-1127

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Palladium(II)-catalyzed direct conversion of allyl arenes into alkenyl nitriles

Z. Shu, Y. Zhou, Y. Zhang and J. Wang, Org. Chem. Front., 2014, 1, 1123 DOI: 10.1039/C4QO00218K

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