Issue 1, 2015
From the journal:

Organic Chemistry Frontiers

Rhodium-catalyzed synthesis of multi-substituted furans from N-sulfonyl-1,2,3-triazoles bearing a tethered carbonyl group†

Wen-Biao Zhang,a   Shi-Dong Xiua  and  Chuan-Ying Li*a  

* Corresponding authors

a Department of Chemistry, Zhejiang Sci-Tech University, Xiasha West Higher Education District, Hangzhou 310018, China
E-mail: licy@zstu.edu.cn

Abstract

The efficient synthesis of highly functionalized furan derivatives from 1-sulfonyl-1,2,3-triazoles with a pendent carbonyl group is reported. The process involves an intramolecular trapping of α-imino carbene and subsequent aromatization.

Graphical abstract: Rhodium-catalyzed synthesis of multi-substituted furans from N-sulfonyl-1,2,3-triazoles bearing a tethered carbonyl group

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Article information

DOI
https://doi.org/10.1039/C4QO00273C
Article type
Research Article
Submitted
22 Oct 2014
Accepted
28 Nov 2014
First published
28 Nov 2014

Org. Chem. Front., 2015,2, 47-50

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Rhodium-catalyzed synthesis of multi-substituted furans from N-sulfonyl-1,2,3-triazoles bearing a tethered carbonyl group

W. Zhang, S. Xiu and C. Li, Org. Chem. Front., 2015, 2, 47 DOI: 10.1039/C4QO00273C

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