Issue 11, 2014

Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes

Abstract

Chiral iminopyridine oxazoline (IPO) ligands were designed, synthesized and utilized for the first cobalt-catalyzed highly regio- and enantioselective anti-Markovnikov hydroboration of 1,1-disubstituted aryl alkenes. These novel IPO ligands will likely be of high value for asymmetric transformations with first-row transition metals.

Graphical abstract: Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes

Supplementary files

Article information

Article type
Research Article
Submitted
10 Nov 2014
Accepted
18 Nov 2014
First published
19 Nov 2014

Org. Chem. Front., 2014,1, 1306-1309

Author version available

Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes

J. Chen, T. Xi, X. Ren, B. Cheng, J. Guo and Z. Lu, Org. Chem. Front., 2014, 1, 1306 DOI: 10.1039/C4QO00295D

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