Issue 1, 2015

Zinc-mediated allylation of carbon dioxide—the LiOAc effect

Abstract

A direct carboxylation reaction of allylic bromides mediated by zinc powder has been developed. The reaction occurred smoothly at room temperature with 1 atm of CO2 provided by a balloon. The reaction was conducted in the presence of LiOAc giving excellent yields. An excellent branched regioselectivity was observed and the reaction was easily scaled-up to 10 gram-scale.

Graphical abstract: Zinc-mediated allylation of carbon dioxide—the LiOAc effect

Supplementary files

Article information

Article type
Research Article
Submitted
13 Nov 2014
Accepted
01 Dec 2014
First published
02 Dec 2014

Org. Chem. Front., 2015,2, 65-68

Zinc-mediated allylation of carbon dioxide—the LiOAc effect

B. Miao and S. Ma, Org. Chem. Front., 2015, 2, 65 DOI: 10.1039/C4QO00300D

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