Role of carbon coating in improving electrochemical performance of Li-rich Li(Li0.2Mn0.54Ni0.13Co0.13)O2 cathode

Abstract

Li-rich Li(Li_0.2Mn_0.54Ni_0.13Co_0.13)O₂ cathode coated with carbon layer has been prepared by a hydrothermal approach followed by a post annealing process. The cathode after surface modification exhibits both enhanced cyclability and improved rate capability compared with the pristine one without coating. The carbon coating process causes a phase transformation from Li₂MnO₃-like domain to cubic-spinel domain with Fdm symmetry at surface regions of particles. As a consequence, the valence state of Mn on the surface accordingly varies. Such transformed surface spinels, as well as the wrapped carbon layers as a result of this coating strategy are believed to be responsible for the enhanced electrochemical performance.