Issue 63, 2014
From the journal:

RSC Advances

Unexpected hydrazine hydrate-mediated aerobic oxidation of aryl/ heteroaryl boronic acids to phenols in ambient air†

Yanzhen Zhong,a   Linxin Yuan,a   Zheng Huang,a   Wenchao Gu,a   Ye Shaoa  and  Wei Han*a  

* Corresponding authors

a Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, Key Laboratory of Applied Photochemistry, School of Chemistry and Materials Science, Nanjing Normal University, Wenyuan Road NO.1, 210023 Nanjing, China
E-mail: whhanwei@gmail.com
Fax: +86-25-8589-1455

Abstract

The expedient and efficient sub-stoichimetric hydrazine hydrate-mediated aerobic hydroxylation of boronic acids that proceeds in poly(ethylene glycol) (PEG-400) has been successfully developed, providing diverse phenols in high yields. And heteroaryl boronic acids are also amenable to this protocol.

Graphical abstract: Unexpected hydrazine hydrate-mediated aerobic oxidation of aryl/ heteroaryl boronic acids to phenols in ambient air

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Article information

DOI
https://doi.org/10.1039/C4RA05589F
Article type
Communication
Submitted
11 Jun 2014
Accepted
14 Jul 2014
First published
16 Jul 2014

RSC Adv., 2014,4, 33164-33167

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Unexpected hydrazine hydrate-mediated aerobic oxidation of aryl/ heteroaryl boronic acids to phenols in ambient air

Y. Zhong, L. Yuan, Z. Huang, W. Gu, Y. Shao and W. Han, RSC Adv., 2014, 4, 33164 DOI: 10.1039/C4RA05589F

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