A chromium-based metal organic framework as a potential high performance adsorbent for anaesthetic vapours

Abstract

In this work, a chromium-based metal organic framework (Cr-MOF) was synthesized, characterized and tested for the adsorption of a model highly ozone-depleting anaesthetic (sevoflurane). Adsorption isotherms were measured at different temperatures e.g., 283, 298, 313 and 328 K on both Cr-MOF and a conventionally used reference adsorbent. At the temperatures used in this study, the Cr-based MOF showed a significantly higher sevoflurane (selected anaesthetic) equilibrium adsorption capacity compared to the reference sample, although adsorption on the selected MOF did not take place on all active sites (i.e., it did not expose its coordinatively unsaturated sites). Moreover, sevoflurane adsorption on Cr-MOF was found to be fully reversible in the 283–328 K temperature range, and the adsorbent was fully regenerated by vacuum treatment at ambient temperature. The semiempirical Sips model was successfully used to fit sevoflurane adsorption data, substantially confirming the phenomenological aspects of the process inferable from the experimental results.