Issue 70, 2014

I2-promoted cross-dehydrogenative coupling of α-carbonyl aldehydes with alcohols for the synthesis of α-ketoesters

Abstract

A facile and efficient method for the synthesis of α-ketoesters from alcohols and α-carbonyl aldehydes has been developed at room temperature under metal-free conditions for the first time. Various alcohols and α-carbonyl aldehydes could participate in this reaction to afford the desired products in excellent yields.

Graphical abstract: I2-promoted cross-dehydrogenative coupling of α-carbonyl aldehydes with alcohols for the synthesis of α-ketoesters

Supplementary files

Article information

Article type
Communication
Submitted
20 Jun 2014
Accepted
06 Aug 2014
First published
21 Aug 2014

RSC Adv., 2014,4, 37047-37050

I2-promoted cross-dehydrogenative coupling of α-carbonyl aldehydes with alcohols for the synthesis of α-ketoesters

A. Sagar, S. Vidyacharan and D. S. Sharada, RSC Adv., 2014, 4, 37047 DOI: 10.1039/C4RA06028H

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