Issue 84, 2014
From the journal:

RSC Advances

Iodine-promoted 2-arylsulfanylphenol formation using cyclohexanones as phenol source†

Ya Chen,a   Fuhong Xiao,a   Hui Chen,a   Saiwen Liua  and  Guo-Jun Deng*ab  

* Corresponding authors

a Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105, China
E-mail: gjdeng@xtu.edu.cn
Fax: +86-0731-5829-2251
Tel: +86-0731-5829-8601

b Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China

Abstract

A novel method for the formation of 2-arylsulfanylphenols using cyclohexanones as phenol source via dehydrogenation is described. Various aromatic sodium sulfinates and sulfonyl chlorides acted as efficient coupling partners to construct new C–S bonds in the presence of an iodine promoter.

Graphical abstract: Iodine-promoted 2-arylsulfanylphenol formation using cyclohexanones as phenol source

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Article information

DOI
https://doi.org/10.1039/C4RA08014A
Article type
Paper
Submitted
02 Aug 2014
Accepted
05 Sep 2014
First published
08 Sep 2014

RSC Adv., 2014,4, 44621-44628

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Iodine-promoted 2-arylsulfanylphenol formation using cyclohexanones as phenol source

Y. Chen, F. Xiao, H. Chen, S. Liu and G. Deng, RSC Adv., 2014, 4, 44621 DOI: 10.1039/C4RA08014A

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