Issue 78, 2014
From the journal:

RSC Advances

Vinylphenylglycidyl ether-based colloidal architectures: high-functionality crosslinking reagents, hybrid raspberry-type particles and smart hydrophobic surfaces†

S. Mehlhase,‡a   C. G. Schäfer,‡a   J. Morsbach,b   L. Schmidt,a   R. Klein,a   H. Frey*b  and  M. Gallei*a  

* Corresponding authors

a Ernst-Berl-Institut für Technische und Makromolekulare Chemie, Technische Universität Darmstadt, Alarich-Weiss-Str. 4, D-64287 Darmstadt, Germany
E-mail: m.gallei@mc.tu-darmstadt.de

b Institute of Organic Chemistry, Organic and Macromolecular Chemistry, Johannes Gutenberg-Universität, Duesbergweg 10-14, D-55099 Mainz, Germany
E-mail: hfrey@uni-mainz.de

Abstract

An efficient synthetic strategy for the preparation of monodisperse colloidal core/shell architectures with reactive epoxy functionalities is reported, based on the bifunctional vinylphenylglycidyl ether monomer. Accessibility of the reactive immobilized epoxy moieties was quantified by UV/vis spectroscopy in an isorefractive medium. Inorganic–organic hybrid raspberry-type architectures revealed a tremendous inpact on the surface wettability of water.

Graphical abstract: Vinylphenylglycidyl ether-based colloidal architectures: high-functionality crosslinking reagents, hybrid raspberry-type particles and smart hydrophobic surfaces

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Article information

DOI
https://doi.org/10.1039/C4RA08382B
Article type
Communication
Submitted
08 Aug 2014
Accepted
27 Aug 2014
First published
28 Aug 2014
This article is Open Access
Creative Commons BY license

RSC Adv., 2014,4, 41348-41352

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Vinylphenylglycidyl ether-based colloidal architectures: high-functionality crosslinking reagents, hybrid raspberry-type particles and smart hydrophobic surfaces

S. Mehlhase, C. G. Schäfer, J. Morsbach, L. Schmidt, R. Klein, H. Frey and M. Gallei, RSC Adv., 2014, 4, 41348 DOI: 10.1039/C4RA08382B

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