Issue 83, 2014

Copper-catalyzed carbonylative Suzuki coupling of aryl iodides with arylboronic acids under ambient pressure of carbon monoxide

Abstract

An efficient and ligandless nanocopper-catalyzed carbonylative cross-coupling of aryl iodides with arylboronic acids at ambient CO pressure in poly(ethylene glycol), has been developed. This protocol is general, practical, and recyclable, and offers an attractive alternative to the corresponding palladium-mediated carbonylative Suzuki process for the construction of biaryl ketone scaffolds.

Graphical abstract: Copper-catalyzed carbonylative Suzuki coupling of aryl iodides with arylboronic acids under ambient pressure of carbon monoxide

Supplementary files

Article information

Article type
Communication
Submitted
13 Aug 2014
Accepted
10 Sep 2014
First published
10 Sep 2014

RSC Adv., 2014,4, 44312-44316

Author version available

Copper-catalyzed carbonylative Suzuki coupling of aryl iodides with arylboronic acids under ambient pressure of carbon monoxide

L. Cheng, Y. Zhong, Z. Ni, H. Du, F. Jin, Q. Rong and W. Han, RSC Adv., 2014, 4, 44312 DOI: 10.1039/C4RA08594A

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