Issue 31, 2015

O2-mediated C(sp2)–X bond oxygenation: autoxidative carbon–heteroatom bond formation using activated alkenes as a linkage

Abstract

Autoxidative carbon–heteroatom bond formation using activated alkenes as a linkage is described. Heteroatom (O, S) nucleophiles could be transformed into different kinds of valuable β-keto compounds via an O2-mediated C(sp2)–X bond oxygenation process, without using any external organic oxidants or metal catalysts.

Graphical abstract: O2-mediated C(sp2)–X bond oxygenation: autoxidative carbon–heteroatom bond formation using activated alkenes as a linkage

Supplementary files

Article information

Article type
Communication
Submitted
26 Dec 2014
Accepted
16 Feb 2015
First published
19 Feb 2015

RSC Adv., 2015,5, 24494-24498

O2-mediated C(sp2)–X bond oxygenation: autoxidative carbon–heteroatom bond formation using activated alkenes as a linkage

Q. Lu, J. Chen, C. Liu, Z. Huang, P. Peng, H. Wang and A. Lei, RSC Adv., 2015, 5, 24494 DOI: 10.1039/C4RA17106C

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