Issue 29, 2015
From the journal:

RSC Advances

Iodine–triphenylphosphine mediated sulfenylation of imidazoheterocycles with sodium sulfinates†

Xuhu Huang,a   Shucheng Wang,a   Bowen Li,a   Xin Wang,a   Zemei Ge*a  and  Runtao Li*a  

* Corresponding authors

a State Key Laboratory of Natural and Biomimetic Drugs, School of Pharmaceutical Sciences, Peking University, Beijing 100191, China
E-mail: zmge@bjmu.edu.cn, lirt@bjmu.edu.cn
Fax: +86 10 82805954
Tel: +86 10 82805954

Abstract

An efficient approach to sulfenyl imidazoheterocycles has been developed via iodine–triphenylphosphine mediated direct sulfenylation of imidazoheterocycles with sodium sulfinates. The reactions proceed smoothly under transition-metal-free conditions with a broad range of substrate scope, giving the desired products in moderate to excellent yields.

Graphical abstract: Iodine–triphenylphosphine mediated sulfenylation of imidazoheterocycles with sodium sulfinates

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Article information

DOI
https://doi.org/10.1039/C4RA17237J
Article type
Communication
Submitted
30 Dec 2014
Accepted
23 Feb 2015
First published
23 Feb 2015

RSC Adv., 2015,5, 22654-22657

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Iodine–triphenylphosphine mediated sulfenylation of imidazoheterocycles with sodium sulfinates

X. Huang, S. Wang, B. Li, X. Wang, Z. Ge and R. Li, RSC Adv., 2015, 5, 22654 DOI: 10.1039/C4RA17237J

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