Issue 28, 2015
From the journal:

Chemical Communications

Rh(iii)-catalyzed oxime ether-directed heteroarylation of arene through oxidative C–H/C–H cross-coupling†

Dekun Qin,a   Jing Wang,a   Xurong Qin,a   Chunxia Wang,a   Ge Gao*a  and  Jingsong You*a  

* Corresponding authors

a Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P. R. China
E-mail: gg2b@scu.edu.cn, jsyou@scu.edu.cn
Fax: +86 28-85412203

Abstract

A rhodium(III)-catalyzed dehydrogenative cross-coupling reaction has been developed for the synthesis of bi(hetero)aryl structures by using oxime ethers as the directing group. This protocol features a relatively broad substrate scope and a good tolerance of functional groups.

Graphical abstract: Rh(iii)-catalyzed oxime ether-directed heteroarylation of arene through oxidative C–H/C–H cross-coupling

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Article information

DOI
https://doi.org/10.1039/C5CC00387C
Article type
Communication
Submitted
15 Jan 2015
Accepted
02 Mar 2015
First published
02 Mar 2015

Chem. Commun., 2015,51, 6190-6193

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Rh(III)-catalyzed oxime ether-directed heteroarylation of arene through oxidative C–H/C–H cross-coupling

D. Qin, J. Wang, X. Qin, C. Wang, G. Gao and J. You, Chem. Commun., 2015, 51, 6190 DOI: 10.1039/C5CC00387C

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