Issue 18, 2015

enantio-Enriched CPL-active helicene–bipyridine–rhenium complexes

Abstract

The incorporation of a rhenium atom within an extended helical π-conjugated bi-pyridine system impacts the chiroptical and photophysical properties of the resulting neutral or cationic complexes, leading to the first examples of rhenium-based phosphors that exhibit circularly polarized luminescence.

Graphical abstract: enantio-Enriched CPL-active helicene–bipyridine–rhenium complexes

Supplementary files

Article information

Article type
Communication
Submitted
16 Jan 2015
Accepted
22 Jan 2015
First published
23 Jan 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 3754-3757

enantio-Enriched CPL-active helicene–bipyridine–rhenium complexes

N. Saleh, M. Srebro, T. Reynaldo, N. Vanthuyne, L. Toupet, V. Y. Chang, G. Muller, J. A. G. Williams, C. Roussel, J. Autschbach and J. Crassous, Chem. Commun., 2015, 51, 3754 DOI: 10.1039/C5CC00453E

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