Issue 35, 2015
From the journal:

Chemical Communications

Nickel-catalysed P–C bond formation via P–H/C–CN cross coupling reactions†

Ji-Shu Zhang,a   Tieqiao Chen,*a   Jia Yanga  and  Li-Biao Han*ab  

* Corresponding authors

a State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China
E-mail: chentieqiao@hnu.edu.cn

b National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan
E-mail: libiao-han@aist.go.jp

Abstract

Nickel-catalysed P–H/C–CN cross coupling reactions take place efficiently under mild reaction conditions affording the corresponding sp2C–P bonds. This transformation provides a convenient method for the preparation of arylphosphines and arylphosphine oxides from the readily available P–H compounds and arylnitriles.

Graphical abstract: Nickel-catalysed P–C bond formation via P–H/C–CN cross coupling reactions

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Article information

DOI
https://doi.org/10.1039/C5CC01182E
Article type
Communication
Submitted
08 Feb 2015
Accepted
20 Mar 2015
First published
20 Mar 2015

Chem. Commun., 2015,51, 7540-7542

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Nickel-catalysed P–C bond formation via P–H/C–CN cross coupling reactions

J. Zhang, T. Chen, J. Yang and L. Han, Chem. Commun., 2015, 51, 7540 DOI: 10.1039/C5CC01182E

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