SCHEDULED MAINTENANCE
An aryl amine attached to the meso position of a porphyrin controls the π-delocalization using a redox process or a protonation/deprotonation centered at the meso-nitrogen. An easily accessible modulated motif affords a switchable near-IR chromophore as reflected by significant changes in absorption and fluorescence spectra.
M. Pawlicki, K. Hurej, K. Kwiecińska, L. Szterenberg and L. Latos-Grażyński, Chem. Commun., 2015, 51, 11362 DOI: 10.1039/C5CC01231G
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