Linearly bridging CO2 in a metal–organic framework

Fei-Yan Yi; Hai-Long Jiang; Zhong-Ming Sun

doi:10.1039/C5CC01244A

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Linearly bridging CO₂ in a metal–organic framework†

Fei-Yan Yi,^a Hai-Long Jiang^b and Zhong-Ming Sun*^a

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* Corresponding authors

^a State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences (CAS), Changchun, Jilin 130022, China
E-mail: szm@ciac.ac.cn
Web: http:////zhongmingsun.weebly.com/

^b Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Suzhou Nano Science and Technology, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China

Abstract

A very rare structurally characterized CO₂-coordinated metal–organic framework was synthesized by a solvothermal reaction. The CO₂ ligand links two open Zn metal centers in a linear and symmetrical μ(O,O′) coordination mode with a C [double bond, length as m-dash] O distance of 1.107(4) Å. The new complex reported here is stable under ambient conditions and may provide a new strategy for CO₂ fixation.

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Article information

DOI: https://doi.org/10.1039/C5CC01244A
Article type: Communication
Submitted: 10 Feb 2015
Accepted: 25 Feb 2015
First published: 25 Feb 2015

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Chem. Commun., 2015,51, 8446-8449

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Linearly bridging CO₂ in a metal–organic framework

F. Yi, H. Jiang and Z. Sun, Chem. Commun., 2015, 51, 8446 DOI: 10.1039/C5CC01244A

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