Issue 31, 2015
From the journal:

Chemical Communications

Two-coordinate hydrido-germylenes†‡

Terrance J. Hadlington,a   Benedikt Schwarze,a   Ekaterina I. Izgorodina*a  and  Cameron Jones*a  

* Corresponding authors

a School of Chemistry, Monash University, P.O. Box 23, Melbourne, VIC, Australia
E-mail: cameron.jones@monash.edu, katya.pas@monash.edu
Web: http://www.monash.edu/science/research-groups/chemistry/jonesgroup

Abstract

The first structurally characterised two-coordinate hydrido-germylenes, :Ge(H)L (L = –N(Ar){Si(OBut3)}, Ar = C6H2{C(H)Ph2}2R-2,6,4; R = Pri (tBuOL†), Me (tBuOL*)), have been prepared, and their dimerisation shown to be thermodynamically unfavourable, largely due to the extreme steric bulk of their amide ligands.

Graphical abstract: Two-coordinate hydrido-germylenes

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Article information

DOI
https://doi.org/10.1039/C5CC01314C
Article type
Communication
Submitted
12 Feb 2015
Accepted
16 Mar 2015
First published
17 Mar 2015

Chem. Commun., 2015,51, 6854-6857

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Two-coordinate hydrido-germylenes

T. J. Hadlington, B. Schwarze, E. I. Izgorodina and C. Jones, Chem. Commun., 2015, 51, 6854 DOI: 10.1039/C5CC01314C

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