Issue 30, 2015
From the journal:

Chemical Communications

Molecular binding behavior of bipyridium derivatives by water-soluble carboxylato-biphen[3]arene†

Junwei Ma,a   Hongmei Deng,a   Suxiang Ma,a   Jian Li,a   Xueshun Jia*a  and  Chunju Li*ab  

* Corresponding authors

a Department of Chemistry, Shanghai University, Shanghai 200444, P. R. China
E-mail: cjli@shu.edu.cn, xsjia@mail.shu.edu.cn

b State Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai 200433, P. R. China

Abstract

Complexation of two types of dicationic bipyridium guests, paraquat derivatives and bis(N-mono-substituted bipyridine) cations, by a negatively charged carboxylato-biphen[3]arene (CBP3) in water is reported. CBP3 could strongly interact with these guests, where charge-transfer and electrostatic interactions play important roles.

Graphical abstract: Molecular binding behavior of bipyridium derivatives by water-soluble carboxylato-biphen[3]arene

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Article information

DOI
https://doi.org/10.1039/C5CC01470K
Article type
Communication
Submitted
17 Feb 2015
Accepted
09 Mar 2015
First published
09 Mar 2015

Chem. Commun., 2015,51, 6621-6624

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Molecular binding behavior of bipyridium derivatives by water-soluble carboxylato-biphen[3]arene

J. Ma, H. Deng, S. Ma, J. Li, X. Jia and C. Li, Chem. Commun., 2015, 51, 6621 DOI: 10.1039/C5CC01470K

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