Issue 37, 2015

A charge-disproportionate ordered state with δ = 0.75 in a chemically sensitive donor/acceptor Dδ+2A2δ layered framework

Abstract

A novel charge-disproportionation state with δ = 0.75 was observed in an electron-donor (D)/-acceptor (A) Dδ+2A2δ layered framework by chemically tuning the electron-donating affinity of D at the boundary between D0.5+2A and D+2A2− phases, which was pressure-sensitive due to the formation of the D+2A2− oxidation state.

Graphical abstract: A charge-disproportionate ordered state with δ = 0.75 in a chemically sensitive donor/acceptor Dδ+2A2δ− layered framework

Supplementary files

Article information

Article type
Communication
Submitted
24 Feb 2015
Accepted
17 Mar 2015
First published
17 Mar 2015

Chem. Commun., 2015,51, 7795-7798

Author version available

A charge-disproportionate ordered state with δ = 0.75 in a chemically sensitive donor/acceptor Dδ+2A2δ layered framework

H. Fukunaga, T. Yoshino, H. Sagayama, J. Yamaura, T. Arima, W. Kosaka and H. Miyasaka, Chem. Commun., 2015, 51, 7795 DOI: 10.1039/C5CC01633A

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