Issue 38, 2015
From the journal:

Chemical Communications

A tetranuclear copper cluster-based MOF with sulfonate–carboxylate ligands exhibiting high proton conduction properties†

Xing Meng,ab   Shu-Yan Song,*a   Xue-Zhi Song,ab   Min Zhu,ab   Shu-Na Zhao,ab   Lan-Lan Wuab  and  Hong-Jie Zhang*a  

* Corresponding authors

a State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625, Renmin Street, Changchun 130022, P. R. China
E-mail: songsy@ciac.ac.cn, hongjie@ciac.ac.cn

b University of Chinese Academy of Sciences, Beijing, China

Abstract

A tetranuclear copper cluster-based MOF with sulfonate–carboxylate ligands has been synthesized. It possesses one-dimensional irregular channels lined with sulfonate, carboxylate, and DMF molecules, which show a high proton conductivity of 7.4 × 10−4 S cm−1 at 95 °C and 95% relative humidity.

Graphical abstract: A tetranuclear copper cluster-based MOF with sulfonate–carboxylate ligands exhibiting high proton conduction properties

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Article information

DOI
https://doi.org/10.1039/C5CC01732G
Article type
Communication
Submitted
27 Feb 2015
Accepted
30 Mar 2015
First published
31 Mar 2015

Chem. Commun., 2015,51, 8150-8152

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A tetranuclear copper cluster-based MOF with sulfonate–carboxylate ligands exhibiting high proton conduction properties

X. Meng, S. Song, X. Song, M. Zhu, S. Zhao, L. Wu and H. Zhang, Chem. Commun., 2015, 51, 8150 DOI: 10.1039/C5CC01732G

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